I hope this is not homework, because it is almost too simple. At the same time, it has an interesting twist. I still fear it is homework. I hope not.
If any solutions do exist, then there will be infinitely many such solutions, since you have one equation with two unknowns. We can think of the general solution locus as an infinite path through the set of complex numbers. And that usually means you can at best solve for one variable in terms of the other.
SO DO SO! Then see if anything interesting happens. The nice thing is this equation is trivially simple to solve. Paper and pencil would suffice, but I am far too lazy, and then there would be no MATLAB context to this question.
eqn = 1/(i + (-50 -25000*R*C*i)/R) == -0.1;
Csol = solve(eqn,C,'returnconditions',true)
Csol =
C: [1×1 sym]
parameters: [1×0 sym]
conditions: [1×1 sym]
Note that the 'returnconditions' clause is necessary here for a valid solution to the problem.
Csol.C
ans =

Csol.conditions
ans = 
So, for ANY value of R, we can compute the value of C from R. I guess we can trivially exclude R==0 there also, since then we would have a divide by zero.
The trick is to look carefully at the condition, what does that tell us? Remember that R must be a real number, containing no imaginary part. Therefore, if we know that
R*(1 - 10i) + 50i = R + (50i - 10i*R)
must be a real number, what does that tell us? The second (fully imaginary) part MUST be zero. There is only one case where that can happen, when R = 5, since we know that R MUST be a real number.
Ergo, the unique fully real solution to the problem has R = 5, and we can find the correspondingly unique value of C, as ...
C = subs(Csol.C,R,5)
C =

No other fully real solution to this particular problem can exist. Other problems may generally be more complicated to solve. Again, could I have done all of this with pencil and paper? Of course.